Barca’s second bid for the 25-year-old, which was rejected immediately, comprised an initial 85m euros (£76.8m) plus 15m euros (£13.5m) in add-ons.
Liverpool have reiterated that Coutinho – who joined them from Inter Milan for £8.5m in 2013 – is not for sale.
Barcelona sold Brazil forward Neymar to Paris St-Germain for a world record transfer of £200m last week.
Coutinho who scored 14 goals last term and spent six weeks out with an ankle injury, signed a new five-year deal in January, which did not include a release clause.
Manager Jurgen Klopp said the Reds were not a “selling club” when Barca’s previous £72m offer was rejected in July, and Liverpool consider the matter closed.
A Freelance Journalist, Entrepreneur and Philanthropist. Editor-in-Chief of www.233times.com. A contributory writer for Ghanaian Chronicle Newspaper. An alumnus of Adisadel College where he read General Arts. He holds first degree in Bachelor of Arts from the University of Ghana; Political Science (major) and History (minor). He has also pursued MSc Corporate Social Responsibility (CSR) and Energy with Public Relations (PR) at the Robert Gordon University in the United Kingdom. His mentors are Rupert Murdoch, Warren Buffet, Sam Jonah, Kwaku Sakyi Addo and Piers Morganview all posts by: Nana Kwesi Coomson
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