The 27-year-old forward, given the role eight months ago but under pressure after recent disciplinary issues, was informed by manager Tite on Saturday.
Alves, 36, will also lead the side in friendlies against Qatar and Honduras.
He has captained Brazil four times, most recently in a 1-0 win over Germany in March 2018.
This month, French football authorities banned Neymar for three matches after he hit a fan following PSG’s defeat by Rennes in the Coupe de France final.
He was also reportedly involved in a dressing room incident with his PSG team-mates.
The Copa America takes place in Brazil from 14 June to 7 July, with the hosts taking on Bolivia, Venezuela and Peru in Group A.
An Entrepreneur and Philanthropist. Editor-in-Chief of www.233times.com. A Senior Journalist with Ghanaian Chronicle Newspaper. An alumnus of Adisadel College where he read General Arts. He holds first degree in Bachelor of Arts from the University of Ghana; Political Science (major) and History (minor). He has also pursued MSc Corporate Social Responsibility (CSR) and Energy with Public Relations (PR) at the Robert Gordon University in the United Kingdom. He is a 2018 Mandela Washington Fellow (YALI) who studied at Clark Atlanta University on the Business and Entrepreneurship track. His mentors are Rupert Murdoch, Warren Buffet, Sam Jonah, Kwaku Sakyi Addo and Piers Morganview all posts by: Nana Kwesi Coomson
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